Suppose you need to prepare 21.0 mL of formate buffer with a ratio of 4 of [sodium formate]/[formic acid] by mixing 0.10 M formic acid and 0

Question

Suppose you need to prepare 21.0 mL of formate buffer with a ratio of 4 of [sodium formate]/[formic acid] by mixing 0.10 M formic acid and 0.10 M sodium formate. How many milliliters of sodium formate do you need to measure to make this buffer (assuming the rest is formic acid)

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Khoii Minh 3 years 2021-07-17T03:11:15+00:00 1 Answers 119 views 0

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    2021-07-17T03:12:30+00:00

    Answer: A volume of 20.49 milliliters of sodium formate do you need to measure to make this buffer (assuming the rest is formic acid).

    Explanation:

    Given: Total volume of the buffer = 21.0 mL

    \frac{[HCOONa]}{[HCOOH]} = 4 … (1)

    It is assumed that the volume of HCOONa is x. Hence, volume of HCOOH is (21.0 – x) mL.

    Hence,

    [HCOONa] = Molarity \times Volume

    = 0.10 \times x

    = 0.1x mmol

    Similarly, [HCOOH] = Molarity \times Volume

    = 0.10 \times (21.0 – x) mmol

    Using equation (1),

    \frac{[HCOONa]}{[HCOOH]} = 4\\\frac{0.1x}{(21.0 - x)} = 4\\0.1x = 84.0 - 4x\\4.1x = 84.0\\x = 20.49 mL

    As x is the volume of sodium formate. Hence, 20.49 mL of sodium formate is required to make the buffer.

    Thus, we can conclude that a volume of 20.49 milliliters of sodium formate do you need to measure to make this buffer (assuming the rest is formic acid).

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