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A certain metal M forms a soluble sulfate salt M2SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 50.0mM soluti
Question
A certain metal M forms a soluble sulfate salt M2SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 50.0mM solution of M2SO4 and the right half cell with a 5.00M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 20.0°C.
Which electrode will be positive?
Left
Right
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Chemistry
3 years
2021-08-22T17:03:31+00:00
2021-08-22T17:03:31+00:00 1 Answers
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Answers ( )
Answer:
Right
Explanation:
The given parameters are;
The soluble sulfate formed by the metal, M = M₂SO₄
In the galvanic cell formed by the metal M, we have;
The concentration of M₂SO₄ in the left half cell = 50.0 mM = 0.05 M
The concentration of M₂SO₄ in the right half cell = 5.00 M
In the galvanic cell, the metal ‘M’ will be dissolved into the solution with lower concentration as M²⁺ which is the left half cell, making the cell negative and the solution more concentrated
In the right half cell, the metal ‘M²⁺’ in the solution will be plated unto the electrode making the solution less concentrated and the electrode in the right half cell will be the positive electrode
Therefore;
The electrode which will be positive is the electrode in the right half cell.